rtupmtni Adrni OXYGEN STABILIZED RARE-EARTH IRON INTERMETALLIC COMPOUNDS*
نویسندگان
چکیده
A new, oxygen-stabilized intermetallic compound was identified in sintered, pre-alloyed rare-earth iron powder samples. Its composition corresponds to formula R.-Fe^Oj, and its crystal structure belongs to space group Imjnu The presence of these compounds has been observed, so far, in several K-Fe-0 systems, with R = Gd, Tb, Dy, Ho* Er and Y.
منابع مشابه
Rare-earth Permanent Magnets: New Magnet Materials and Applications
The introduction of rare-earth permanent magnets based on samarium-cobalt in about 1970, and neodymium-iron-boron magnets in the mid-nineteen eighties, has ushered in a new era in hard magnetic materials. This has resulted in a dramatic improvement in permanent magnet performance, with neodymium-iron-boron (Nd2Fe14B) magnets having a magnetic energy product up to an order of magnitude greater t...
متن کاملIdentifying Transition Metal Contribution to the Rare- Earth L2-Edge XMCD Spectra in R-T Intermetallics
We report on a transition metal contribution to the rare-earth L2-edge XMCD spectrum of intermetallic rareearth transition metal compounds (R-T). The shape and location of this contribution is independent on both the specific rare-earth and the specific 3d metal in the compound. The evolution of the signal with the 3d content indicates that the signal is proportional to the number of T neighbor...
متن کاملMössbauer spectral study of the R
The paper presents an iron-57 Mössbauer spectral study of RFe11.5Ta0.5, with R=Tb, Dy, Ho, Er, Lu, and an evaluation of the different contributions to the hyperfine magnetic fields. The Mössbauer spectra have been analyzed with a model that considers both the distribution of the tantalum atoms in the near-neighbor environment of the iron atoms and the relative orientation of the hyperfine field...
متن کاملIntermetallic charge transfer between A-site Cu and B-site Fe in A-site-ordered double perovskites
In this review article, we describe in detail the temperature-induced intermetallic charge transfer between A-site Cu and B-site Fe ions in the A-site-ordered double perovskites RCu3Fe4O12 (R = La, Bi). In these compounds, a very rare Cu valence state at the square-planar-coordinated A sites was stabilized by high-pressure synthesis. By increasing the temperature, a Cu–Fe intermetallic charge t...
متن کاملValence, coordination number, and PAV cells in metallic rare earth compounds
— Polyhedral atomic volumes, Voronoi volumes, generalized coordination numbers, and Pauling's metallic valences are given for 24 intermetallic rare earth compounds. The results clearly indicate that as much as 33 % rare earth isovalent volume contraction can occur upon compound formation while the atomic volumes of aluminum and the transition elements are nearly constant. Earlier discussions of...
متن کامل